基于對稱及不對稱富烯配體、雙1，3，4-Oxadiazole雜環(huán)有機配體及柔性Schiff-base配體的有機-無機配位聚合物及超分子的合成及性質(zhì)研究.pdf

1、山東師范大學(xué)碩士學(xué)位論文基于對稱及不對稱富烯配體、雙1，3，4Oxadiazole雜環(huán)有機配體及柔性Schiffbase配體的有機無機配位聚合物及超分子的合成及性質(zhì)研究姓名：耿琰申請學(xué)位級別：碩士專業(yè)：有機化學(xué)指導(dǎo)教師：董育斌20050420山東師范人學(xué)順I(yè)。學(xué)位論文AbstractThechemistryoforganic—inorganiccoordinationpolymershasrecentlybecomeareaofincr

2、easinginterestSelfassemblyoforganicligandsandinorganicmetalionsisoneofthemostefficientandwidelyusedapproachesfortheconstructionoforganic—inorganiccompositematerialsInthethesis，aseriesofnovelsymmetricorunsymmetricfulvenel

3、igandswithfive—memberedheterocyclicring—containingasterminalcoordinationsitesweresynthesizedThecoordinationchemistryofthesenovelligandswithtransitionmetalionswasinvestigatedInaddition，twobi1，3，4oxadiazole—containingligan

4、dsandfiveflexibleschiffbaseligandshavebeendesignedandsynthesizedthecoordinationchemistrybasedonthemwithmetalionsWaSinvestigated，tooTotally22newcoordinationpolymerswerepreparedbysolutionreactionsandfullycharacterizedbyIR，

5、elementalanalysisandsinglecrystalXraydiffraction，1EighteennewAgcontainingcoordinationpolymericcompoundsgeneratedfromthenewfulveneligandsandAgX(X2C104SbF6’OTf’，PF6’)havebeensynthesized：[A92(L1)3】(S03CF3)2(1)，[Ag(L1)]C104(

6、2)，[Ag(L1)(C6H6)SbF6】05(c6H6)(H20)(3)，[Ag(L15)]S03CF3(4)，【Ag(L2)S03CF3]’05(C6H6)(5)，[A92(L2)2(s03CF3)2]2(C6H6)(6)，[Ag(L2)(SbF6)O5L“bis’C6H6)】‘H20(7)，[Ag(L2)(H2P04)】05(c6H6)(8)，[Ag(L3)(SbF6)】‘(C7H8)(9)，[Ag(L3)]PF6(c7H8)(1

7、0)，【AgL4]S03CF3(11)’[AgL5(H20)]S03CF3(12)，[A93(L6)2](C104)3“2(C6H6)(13)，([Ag(LS)]SbF6‘(C7H8)‘05(c6H6)(14)，[Ag(L8)]S03CF3(15)，[Ag(L10)(C6H6)]PF6(16)，([A92(L12)(C6H6)(SbF6)】SbF6)25(C6H6)(17)’[Ag(L13)(S03CF3)】。05(c6H6)(18)T

8、heirsinglecrystalstructuresandluminescentpropertieswereinvestigatedinthesolidstate2TwonewAgO)containingcoordinationpolymericcompoundsbasedonbi一1，3，4oxadiazole—containingligands(L17)，namelyAg(L17)PF6(19)andAg(L17)S01CFl(2

9、0)wereobtainedTheirsinglecrystalstructureswereinvestigatedinthesolidstate3TwonewHg(U)一containingcoordinationpolymericcompoundsbasedonflexibleschiffbaseligands(L20)，namelyHgBr2(L20)’CH]OH(21)，Hgl2(L20)‘CH30H(22)wereobtain